16-04

A.A.C. Bode, S.J.C. Granneman, M.C. Feiters, P. Verwer, S. Jiang, J.A.M. Meijer, W.J.P. van Enckevort, E. Vlieg,

Structure and activity of the anticaking agent iron(III) meso-tartrate

Dalton Trans. 45 (2016) 6650-6659

Abstract

Iron(III) meso-tartrate, a metal–organic complex, is a new anticaking agent for sodium chloride. A molecular structure in solution is proposed, based on a combination of experimental and molecular modelling results. We show that the active complex is a binuclear iron(III) complex with two bridging meso-tartrate ligands. The iron atoms are antiferromagnetically coupled, resulting in a reduced paramagnetic nature of the solution. In solution, a water molecule coordinates to each iron atom as a sixth ligand, resulting in an octahedral symmetry around each iron atom. When the water molecule is removed, a flat and charged site is exposed, matching the charge distribution of the {100} sodium chloride crystal surface. This charge distribution is also found in the iron(III) citrate complex, another anticaking agent. This gives a possible

adsorption geometry on the crystal surface, which in turn explains the anticaking activity of the iron(III) meso-tartrate complex.